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Ultrafast dynamics in polycyclic aromatic hydrocarbons: the key case of conical intersections at higher excited states and their role in the photophysics of phenanthrene monomer

Type of publication Peer-reviewed
Publikationsform Original article (peer-reviewed)
Author Nazari M., Bösch C. D., Rondi A., Francés-Monerris A., Marazzi M., Lognon E., Gazzetto M., Langenegger S. M., Häner R., Feurer T., Monari A., Cannizzo A.,
Project From DNA-Assembled Oligochromophores to Supramolecular Polymers: Aromatic Oligophosphates as Versatile Building Blocks for Functional Materials
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Original article (peer-reviewed)

Journal Physical Chemistry Chemical Physics
Volume (Issue) 21(31)
Page(s) 16981 - 16988
Title of proceedings Physical Chemistry Chemical Physics
DOI 10.1039/c9cp03147b

Open Access

URL http://doi.org/10.1039/C9CP03147B
Type of Open Access Publisher (Gold Open Access)

Abstract

Proper interpretation of phenanthrene's and similar PAHs’ photocycle relies on two higher excited state relaxations due to the simultaneous presence of non-adiabatic and adiabatic transitions.
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