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Triazacyclohexane (tach) Complexes of High-Valent Rhenium: Syntheses of [(R(3)tach)ReO3](+) (R = -CH3, -CH2C6H5) and Its Substitution Reactions

Type of publication Peer-reviewed
Publikationsform Original article (peer-reviewed)
Author Braband H, Imstepf S, Felber M, Spingler B, Alberto R,
Project Technetium Chemistry at High Oxidation States: New Perspectives for Nanomaterials and Polyoxometalates in Medicine and Environmental Science
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Original article (peer-reviewed)

Journal INORGANIC CHEMISTRY
Volume (Issue) 49(4)
Page(s) 1283 - 1285
Title of proceedings INORGANIC CHEMISTRY

Abstract

N-Alkylated derivatives of 1,3,5-triazacyclohexane (tach) are versatile, facially coordinating ligands. We present the syntheses and full characterization of two new complexes of the [(R3tach)ReO3]+ type. In these complexes, the tach ligand is readily substituted by bi- and tridentate ligands; hence, they can be considered as sources of the [ReO3]+ motif for ReVII complexes.
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