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One-dimensional quantum magnetism in the anhydrous alum KTi(SO4)(2)

Type of publication Peer-reviewed
Publikationsform Original article (peer-reviewed)
Publication date 2015
Author Nilsen G. J., Araja A., Tsirlin A. A., Mutka H., Kasinathan D., Ritter C., Ronnow H. M.,
Project Mott Physics Beyond the Heisenberg Model in Iridates and Related Materials
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Original article (peer-reviewed)

Journal NEW JOURNAL OF PHYSICS
Volume (Issue) 17
Page(s) 113935
Title of proceedings NEW JOURNAL OF PHYSICS
DOI 10.1088/1367-2630/17/11/113035

Open Access

Abstract

The anhydrous alum KTi(SO4)2, where the Ti3+ (d1, S = 1/2) ions form an anisotropic triangular lattice, has been prepared by a new hydrothermal route and characterized by magnetic susceptibility and neutron scattering measurements. Contrary to expectations, fits to the magnetic susceptibility indicate that the spins are isotropic (i.e. Heisenberg) and that the frustrating couplings are weak; indeed, the system is well modelled by nearly isolated chains. The inelastic neutron scattering data furthermore shows excellent agreement with an exact theoretical calculation for the one-dimensional spinon continuum. The unexpected magnetic properties of KTi(SO4)2 are explained in the light of density functional calculations, which reveal an unusual orbital ground state for the Ti3 + ion.
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