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Enargite-luzonite hydrothermal vents in Manus Back-Arc Basin: Submarine analogues of high-sulfidation epithermal mineralization

Type of publication Peer-reviewed
Publikationsform Original article (peer-reviewed)
Publication date 2016
Author Dekov Vesselin, Rouxel Olivier, Kouzmanov Kalin, Bindi Luca, Asael Dan, Fouquet Yves, Etoubleau Joël, Burgaud Gaëtan, Wälle Markus,
Project Chemistry and P-T of fluids trapped in co-genetic opaque ore and transparent gangue minerals: What are the real ore-precipitating fluids?
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Original article (peer-reviewed)

Journal Chemical Geology
Volume (Issue) 438
Page(s) 36 - 57
Title of proceedings Chemical Geology
DOI 10.1016/j.chemgeo.2016.05.021


Active and inactive hydrothermal chimneys composed almost entirely of enargite and luzonite, rare minerals in seafloor hydrothermal deposits, were found at the summits of two submarine volcanoes, North Su and Kaia Natai, in the Manus Back-Arc Basin. Detailed mineralogical and geochemical studies revealed that most probably these deposits precipitated at T = 200°–330 °C and high fS2. The negative δ34S values (−8.58 to −3.70‰)ofthe enargite-luzonite are best explained by disproportionation reactions of magmatic SO2 and suggest that the high fS2 is likely provided by direct magmatic input of SO2 into the hydrothermal system. Fractionation of Cu sta-ble isotopes during the precipitation of enargite-luzonite (δ65Cu ranges from −0.20 to +0.35‰)isinferredtobe associated with either Rayleigh-type fractionation, or redox processes (Cu+ oxidation to Cu2+) and the mass bal-ance of dissolved Cu+ and Cu2+ species in the hydrothermal fluid. The trace element composition of enargite and luzonite indicates a temporal fluctuation of the chemistry of the ore-forming fluid with an increase of Fe, Ga, Tl, Au, Hg, Pb and Ag, and decrease of Sb, Sn, Te, Ge and V concentrations with time and points out that this type of deposits is the richest in Au (average 11.9 ppm) and Te (average 169 ppm) among all other types of seafloor metal deposits. In addition to the widespread inorganic precipitation of enargite and luzonite in this setting, there is evidence that this mineralization may be biogenically mediated on the external surfaces of the active vents. Fungi-like fil-aments mineralized by luzonite imply that the fungi (Dikarya subkingdom) may be implicated in a mechanism of bio-sequestration of As, S and Cu, and provide the initial substrate for luzonite precipitation. The studied enargite-luzonite deposits have characteristics similar to those of subaerial high-sulfidation epithermal mineralization: back-arc basin setting; acid-sulfate and boiling ore-forming fluids; altered (advanced argillic stage) dacitic host rocks; major enargite-luzonite and minor pyrite, barite and S0; δ34S b 0‰. Therefore, they may be considered as submarine analogues of subaerial high-sulfidation epithermal deposits with the po-tential for concealed porphyry Cu(\\Au) mineralization at depth.