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"Off-axis" metal-metal bond in Mn2(CO)10 at high pressure

Type of publication Peer-reviewed
Publikationsform Original article (peer-reviewed)
Publication date 2014
Project Chemical bonding and reactions in molecular crystals at high pressure
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Original article (peer-reviewed)

Journal Chemical Communiation
Volume (Issue) 50
Page(s) 12824 - 128247
Title of proceedings Chemical Communiation
DOI 10.1039/c4cc04152f

Open Access

URL http://boris.unibe.ch/67488/8/Macchi_Mn2CO10_HP_acceptedversion.pdf
Type of Open Access Repository (Green Open Access)

Abstract

At variance with what was previously reported, Mn2(CO)10 does not transform its conformation from staggered to eclipsed in the high pressure crystal form. X-ray powder diffraction, DFT calculations and Raman spectroscopy show that the staggered conformation is retained. Instead, a rotation and a translation of the Mn(CO)5 pyramidal units produce an ‘‘off-axis’’ and rather shorter Mn–Mn bond.
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