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Extraordinarily Efficient Conduction in a Redox-Active Ionic Liquid

Type of publication Peer-reviewed
Publikationsform Original article (peer-reviewed)
Publication date 2011
Author Thorsmolle VK, Rothenberger G, Topgaard D, Brauer JC, Kuang DB, Zakeeruddin SM, Lindman B, Gratzel M, Moser JE,
Project THz time-domain spectroscopy of unconventional photonic and charge transport systems
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Original article (peer-reviewed)

Journal CHEMPHYSCHEM
Volume (Issue) 12(1)
Page(s) 145 - 149
Title of proceedings CHEMPHYSCHEM
DOI 10.1002/cphc.201000819

Open Access

Abstract

Iodine added to iodide-based ionic liquids leads to extraordinarily efficient charge transport, vastly exceeding that expected for such viscous systems. Using terahertz time-domain spectroscopy, in conjunction with dc conductivity, diffusivity and viscosity measurements we unravel the conductivity pathways in 1-methyl-3-propylimidazolium iodide melts. This study presents evidence of the Grotthuss mechanism as a significant contributor to the conductivity, and provides new insights into ion pairing processes as well as the formation of polyiodides. The terahertz and transport results are reunited in a model providing a quantitative description of the conduction by physical diffusion and the Grotthuss bond-exchange process. These novel results are important for the fundamental understanding of conduction in molten salts and for applications where ionic liquids are used as charge-transporting media such as in batteries and dye-sensitized solar cells.
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