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New Magnetic Frameworks of [(CuF2(H2O)2)x(pyz)]

Type of publication Peer-reviewed
Publikationsform Original article (peer-reviewed)
Publication date 2014
Project Chemical bonding and reactions in molecular crystals at high pressure
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Original article (peer-reviewed)

Journal Chemical Communication
Volume (Issue) 50
Page(s) 14504 - 14507
Title of proceedings Chemical Communication
DOI 10.1039/c4cc06696k

Open Access

Type of Open Access Publisher (Gold Open Access)


Pressure-driven orbital reordering in the quantum magnet [CuF2(H2O)2-(pyz)], (pyz = pyrazine), dramatically affects its magnetic exchange interactions. The crystal chemistry of this system is enriched with a new phase above 3 GPa, surprisingly concomitant with other polymorphs. Moreover, we discovered an unprecedented compound with a different stoichiometry, [(CuF2(H2O)2)2(pyz)], featuring magnetic bi-layers.