Data and Documentation
Open Data Policy
FAQ
EN
DE
FR
Suchbegriff
Advanced search
Project
Back to overview
Functional, Carbon-Rich, Nanostructured Materials for Applications at the Interface of Optoelectronics and the Biosciences
English title
Functional, Carbon-Rich, Nanostructured Materials for Applications at the Interface of Optoelectronics and the Biosciences
Applicant
Frauenrath Holger
Number
113509
Funding scheme
Project funding (Div. I-III)
Research institution
Departement Materialwissenschaft ETH Zürich
Institution of higher education
ETH Zurich - ETHZ
Main discipline
Organic Chemistry
Start/End
01.10.2006 - 30.09.2008
Approved amount
123'718.00
Show all
Keywords (11)
Self-Assembly; Rodcoil Molecules; Oligoynes; Graphitzization; Graphite Ribbons; Polymer Synthesis; Carbon-Rich Materials; Nanostructured Materials; Conducting Polymers; Supramolecular Self-Assembly; Topochemical Reactions
Lay Summary (English)
Lead
Lay summary
The research project aims to prepare and investigate organic materials which may create a bridge between the worlds of microelectronics and biology which is one of the current challenges in nanotechnology.
Such materials should "speak the language" of the biomaterials they are supposed to interact with. Many biomaterials achieve their highly specialized and often extraordinary properties with hierarchical structure formation, i.e., the presence and control of structural order on different length scales. Therefore, the targeted synthetic materials ought to provide the chemical functionality for an interaction with biological systems on the molecular level, and also exhibit a similar degree of hierarchical structure formation in order to "mimic" the functioning of the latter. At the same time, they should also provide properties that are not general features of biomaterials, such as electric (semi-) conductivity, which may make them targets for applications in combination with microelectronic devices.
As the control of secondary and higher structure formation in synthetic polymers is still a challenge, we decided to make use of supramolecular self-assembly for this purpose. We plan to prepare molecules which, due to their molecular structure, spontaneously self-organize into aggregates with well-defined hierarchical structures. The molecules are envisioned to contain diacetylene or higher oligoyne functions, which are to serve as carbon-only precursors for carbon-rich, potentially conducting materials, such as graphitic ribbons with a width of a few nanometers. The conversion of the molecular precursors into covalent organic materials is envisioned to be achieved within the supramolecular aggregates under retention of their hierarchical structure. The result would, therefore, be optoelectronically active organic materials with a high degree of chemical functionalization and, likewise, well-defined hierarchical structure.These materials as well as their precursors are to be characterized with advanced spectroscopic as well as imaging techniques, and they are going to be investigated with respect to their materials properties.
Direct link to Lay Summary
Last update: 21.02.2013
Responsible applicant and co-applicants
Name
Institute
Frauenrath Holger
Laboratoire des matériaux organiques et macromoléculaires EPFL - STI - IMX - LMOM
Employees
Name
Institute
Xu Rui
Gebers Jan
Associated projects
Number
Title
Start
Funding scheme
121812
Optoelectronically Active Materials and Functional Graphite nanostructures from ologopeptide-Substituted Conjugated Molecules
01.10.2009
Project funding (Div. I-III)
-